At a given apparent weight (ie mass x g load) the stalling AOA and stalling speed are nearly constant (ignoring hysterysis and rapid onset variations)
However, as an aircraft can fly at varying mass (payload/fuel/structural/equipment) according to configuration, and it manoeuvres almost entirely by altering the g-load (by changing the AOA) it can be seen that stalling speed will vary enormously (a 6g capable airframe with a 50% useful load will have a range of stalling speeds with a factor of 3 (ie 100KIAS and 300KIAS) - It will probably not be capable of much more than 6g at low weights, even if it remains capable at nominal MTO, as many fittings (eg equipment, engines, fuel tanks and lines, pilot seat, instruments are only mounted to '6g' (plus the usual safety factors) mountings.) By comparison, the AOA at which airflow separates will be nearly constant - the character of the stall will usually be sharper and with more buffet and rates after the break when loaded to above 1g, but the orientation or load/airspeed will have little difference to 'when' the aircraft stalls. (Ie you can stall while diving vertically, if the AOA increases too much during a pull-out manoeuvre.